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MATERIAL SAFETY DATA SHEET MOLYDAG 208, PASTE 3. HAZARDS IDENTIFICATION Harmful if swallowed. Vapours are mildly irritating to eyes and respiratory tract. See "Other Health Effects" Section. Can decompose at high temperatures forming toxic gases. Contents may develop pressure on prolonged exposure to heat. EMERGENCY OVERVIEW: POTENTIAL HEALTH EFFECTS Product is irritating to the nose, throat and respiratory tract. See "Other Health Effects" Section.Inhalation: EMERGENCY TELEPHONE NUMBERS (FOR EMERGENCIES INVOLVING CHEMICAL SPILLS OR RELEASE) Toronto, ON (416) 226-6117 Montreal, QC (514) 861-1211 Winnipeg, MB (204) 943-8827 Edmonton, AB (780) 424-1754 Calgary, AB (403) 263-8660 Vancouver, BC (604) 685-5036 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Brenntag Canada Inc. 43 Jutland Rd. Toronto, ON M8Z 2G6 (416) 259-8231 Website: http:\\www.brenntag.ca WHMIS#: 00068497 Index: 2007 November 30 PRODUCT IDENTIFICATION Molydag 208, Paste.Product Name: 2007 November 30Date of Revision: Effective Date: HCI7637/07D Not available.Chemical Name: Molydag 208.Synonyms: Mixture of Molybdenum Disulphide, Petroleum Oil and Additives.Chemical Family: Not available.Molecular Formula: Additive for lubricants and paints. Lubricant.Product Use: WHMIS Classification / Symbol: READ THE ENTIRE MSDS FOR THE COMPLETE HAZARD EVALUATION OF THIS PRODUCT. Not regulated. Ingredient CAS# ACGIH TLV % Concentration 2. COMPOSITION, INFORMATION ON INGREDIENTS (Not Intended As Specifications) Molybdenum Disulphide 1317-33-5 10 mg/m³ (I) 40 - 70 Solvent Refined Residual Oil 64742-01-4 — 10 - 30 Petroleum Oil 64741-88-4 (5 mg/m³ (O)) 5 - 10 The identity of one or more of the ingredient(s) of this product have not been disclosed by our supplier(s) and we are not aware of any additional health hazards due to these ingredients, which are not already identified on this MSDS. Molydag 208, Paste Brenntag Canada Inc. Date of Revision: 2007 November 30WHMIS Number : 00068497 Page 2 of 7 4. FIRST AID MEASURES FIRST AID PROCEDURES If respiratory problems arise, move the victim to fresh air. Give artificial respiration ONLY if breathing has stopped. Give cardiopulmonary resuscitation (CPR) if there is no breathing AND no pulse. Obtain medical advice IMMEDIATELY. Inhalation: Start flushing while removing contaminated clothing. Wash affected areas thoroughly with soap and water. If irritation, redness, or a burning sensation develops and persists, repeat flushing and obtain medical attention. Skin Contact: Immediately flush eyes with running water for a minimum of 20 minutes. Hold eyelids open during flushing. If irritation persists, repeat flushing. Obtain medical attention IMMEDIATELY. Eye Contact: Do not attempt to give anything by mouth to an unconscious person. If victim is alert and not convulsing, rinse mouth out and give 1/2 to 1 glass of water to dilute material. DO NOT induce vomiting. If spontaneous vomiting occurs, have victim lean forward with head down to avoid breathing in of vomitus, rinse mouth and administer more water. Obtain medical attention IMMEDIATELY. Ingestion: This product contains materials that may cause severe pneumonitis if aspirated. If ingestion has occurred less than 2 hours earlier, carry out careful gastric lavage; use endotracheal cuff if available, to prevent aspiration. Observe patient for respiratory difficulty from aspiration pneumonitis. Give artificial resuscitation and appropriate chemotherapy if respiration is depressed. Medical conditions that may be aggravated by exposure to this product include neurological, cardiovascular and skin disorders, diseases of the skin, eyes or respiratory tract. Note to Physicians: Prolonged, confined (especially under the finger nails, under rings or watch bands) or repeated exposure may cause skin irritation. May cause defatting, drying and cracking of the skin. Prolonged and repeated contact may lead to dermatitis. Skin Contact: Not likely to be absorbed through the skin.Skin Absorption: Product residues on fingers, hands or gloves may contact the eyes and cause eye irritation, redness and pain. Eye Contact: This product may cause mild gastrointestinal discomfort.Ingestion: Effects (irritancy) on the skin and eyes may be delayed, and damage may occur without the sensation or onset of pain. Strict adherence to first aid measures following any exposure is essential. May cause central nervous system (CNS) depression. CNS depression is characterized by headache, dizziness, drowsiness, nausea, vomiting and incoordination. Severe overexposures may lead to coma and possible death due to respiratory failure. Other Health Effects: 5. FIRE-FIGHTING MEASURES Flashpoint (°C) AutoIgnition Temperature (°C) LEL UEL Flammability Limits in Air (%): 196. (3) Not available. Not available. Not available. Not regulated.Flammability Class (WHMIS): Thermal decomposition products are toxic and may include oxides of carbon, molybdenum, sulphur and irritating gases. Hazardous Combustion Products: Closed containers exposed to heat may burst. Spilled material may cause floors and contact surfaces to become slippery. Unusual Fire or Explosion Hazards: Not expected to be sensitive to mechanical impact.Sensitivity to Mechanical Impact: Not available.Rate of Burning: Not available.Explosive Power: Not expected to be sensitive to static discharge.Sensitivity to Static Discharge: EXTINGUISHING MEDIA Alcohol resistant foam. Dry Chemical. Carbon Dioxide.Fire Extinguishing Media: FIRE FIGHTING INSTRUCTIONS Molydag 208, Paste Brenntag Canada Inc. Date of Revision: 2007 November 30WHMIS Number : 00068497 Page 3 of 7 Isolate materials that are not involved in the fire and protect personnel. Cool containers with flooding quantities of water until well after the fire is out. Fire-exposed containers should be kept cool by spraying with water to reduce pressure. Instructions to the Fire Fighters: Use self-contained breathing apparatus and protective clothing.Fire Fighting Protective Equipment: 6. ACCIDENTAL RELEASE MEASURES Information in this section is for responding to spills, leaks or releases in order to prevent or minimize the adverse effects on persons, property and the environment. There may be specific reporting requirements associated with spills, leaks or releases, which change from region to region. In all cases of leak or spill contact vendor at Emergency Number shown on the front page of this MSDS. Utilize a spill kit, if available. Spilled material may cause floors and contact surfaces to become slippery. Do not use combustible materials such as sawdust as an absorbent. Eliminate all sources of ignition. Collect product for recovery or disposal. For release to land, or storm water runoff, contain discharge by constructing dykes or applying inert absorbent; for release to water, utilize damming and/or water diversion to minimize the spread of contamination. Ventilate enclosed spaces. Notify applicable government authority if release is reportable or could adversely affect the environment. Containment and Clean-Up Procedures: 7. HANDLING AND STORAGE HANDLING Use normal "good" industrial hygiene and housekeeping practices. Containers exposed to heat may be under internal pressure. These should be cooled and carefully vented before opening. A face shield and apron should be worn. Vent container frequently, and more often in warm weather, to relieve pressure. Handling Practices: See Section 8, "Engineering Controls".Ventilation Requirements: Use only with adequate ventilation and avoid breathing aerosols ( vapours or mists ). Avoid contact with eyes, skin or clothing. Wash thoroughly with soap and water after handling. Wash contaminated clothing thoroughly before re-use. Other Precautions: STORAGE See below.Storage Temperature (°C): General exhaust is acceptable.Ventilation Requirements: Store in a cool, well-ventilated area. Keep away from heat, sparks and flames. Keep containers closed. Do not expose sealed containers to temperatures above 40° C. Avoid freezing! Storage Requirements: Materials of construction for storing the product include: pail. Confirm suitability of any material before using. Special Materials to be Used for Packaging or Containers: 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Recommendations listed in this section indicate the type of equipment, which will provide protection against overexposure to this product. Conditions of use, adequacy of engineering or other control measures, and actual exposures will dictate the need for specific protective devices at your workplace. ENGINEERING CONTROLS General exhaust is acceptable. Local exhaust ventilation preferred. Make up air should be supplied to balance air that is removed by local or general exhaust ventilation. Ventilate low lying areas such as sumps or pits where dense vapours may collect. Engineering Controls: PERSONAL PROTECTIVE EQUIPMENT (PPE) Safety glasses with side shields are recommended to prevent eye contact. Use chemical safety goggles when there is potential for eye contact. Contact lenses should not be worn when working with this material. Eye Protection: Gloves and protective clothing made from neoprene or nitrile rubber should be impervious under conditions of use. Prior to use, user should confirm impermeability. Discard contaminated gloves. Skin Protection: Molydag 208, Paste Brenntag Canada Inc. Date of Revision: 2007 November 30WHMIS Number : 00068497 Page 4 of 7 No specific guidelines available. Respiratory protection should not be necessary unless the material is heated or a mist created. Do not use compressed oxygen in hydrocarbon atmospheres. A NIOSH/MSHA-approved air-purifying respirator equipped with organic vapour cartridges for concentrations up to 50 mg/m³. Use an air-supplied respirator if concentrations are high or unknown. If while wearing a respiratory protection, you can smell, taste or otherwise detect anything unusual, or in the case of a full facepiece respirator you experience eye irritation, leave the area immediately. Check to make sure the respirator to face seal is still good. If it is, replace the filter, cartridge or canister. If the seal is no longer good, you may need a new respirator. (4) Respiratory Protection: Wear regular work clothing. The use of coveralls is recommended. Locate safety shower and eyewash station close to chemical handling area. Take all precautions to avoid personal contact. Other Personal Protective Equipment: None established for this product. EXPOSURE GUIDELINES SUBSTANCE ACGIH TLV (STEL) OSHA PEL (TWA) (STEL) NIOSH REL (TWA) (STEL) Petroleum Oil 10 mg/m³ 5 mg/m³ Oil Mist --- 5 mg/m³ Oil Mist 10 mg/m³ (Oil Mist; Ceiling) Paste. Dark-grey paste. Characteristic odour. Not available. 260. (3) Not available. 0.1. (3) Not available. 1.78. (3) 1 780 kg/m3. Not available. Not available. Not soluble in water. Not available. Not available. Not available. 0. (3) Physical State: Appearance: Odour: Odour Threshold (ppm): Boiling Range (°C): Melting/Freezing Point (°C): Vapour Pressure (mm Hg at 20° C): Vapour Density (Air = 1.0): Relative Density (g/cc): Bulk Density: Viscosity: Evaporation Rate (Butyl Acetate = 1.0): Solubility: % Volatile by Volume: pH: Coefficient of Water/Oil Distribution: Volatile Organic Compounds (VOC): 9. PHYSICAL AND CHEMICAL PROPERTIES (Not intended as Specifications) 11. TOXICOLOGICAL INFORMATION TOXICOLOGICAL DATA: 10. STABILITY AND REACTIVITY CHEMICAL STABILITY Stable.Under Normal Conditions: Not flammable.Under Fire Conditions: Will not occur.Hazardous Polymerization: High temperatures, sparks, open flames and all other sources of ignition. Keep from freezing. Keep tightly closed to protect quality. Conditions to Avoid: Strong oxidizers. Lewis or mineral acids.Materials to Avoid: Thermal decomposition products are toxic and may include oxides of carbon, molybdenum, sulphur and irritating gases. Decomposition or Combustion Products: Molydag 208, Paste Brenntag Canada Inc. Date of Revision: 2007 November 30WHMIS Number : 00068497 Page 5 of 7 SUBSTANCE LD50 (Oral, Rat) LD50 (Dermal, Rabbit) LC50 (Inhalation, Rat, 4h) Molybdenum Disulphide > 6 000 mg/kg (4) --- > 2 820 mg/m³ (1) Petroleum Oil > 15 000 mg/kg (3) > 2 000 mg/kg (3) --- The ingredient(s) of this product is (are) not classed as carcinogenic by ACGIH, IARC, OSHA or NTP.Carcinogenicity Data: No adverse reproductive effects are anticipated.Reproductive Data: No adverse mutagenic effects are anticipated.Mutagenicity Data: No adverse teratogenic effects are anticipated.Teratogenicity Data: None known.Respiratory / Skin Sensitization Data: None known.Synergistic Materials: Molybdenum Disulphide gave negative mutagenic results in short-term bacterial assays. (4) Molybdenum Disulphide is insoluble. Molybdenum Disulphide is poorly absorbed from the lungs or intestinal tract. (4) Rats were fed up to 500 mg for 44 days without ill effects. The ingested molybdenum was excreted in the feces and urine. (4) There have been no reports of skin or eye irritation due to Molybdenum Disulphide. (4) Guinea pigs exposed to very high concentrations (about 600 mg/m³) of Molybdenite ore (Molybdenum Disulphide) for 1 hour/day, 5 days/week for 5 weeks experienced no adverse effects except for shortness of breath during exposure. (Note that Molybdenite ore also contains silicates.) (4) Very little Molybdenum Disulphide was absorbed from the lungs into the blood (1 mg/Kg tissue). Most remained in the lungs. (4) Petroleum Oils are probably not irritating or are only very mildly irritating to skin and eyes. (4) Severely solvent-refined Petroleum Oils have undergone processing which has significantly reduced or removed potentially carcinogenic 3-7 ring polycyclic aromatic hydrocarbons (polynuclear aromatic hydrocarbons (PAHs)). (4) Other Studies Relevant to Material: 12. ECOLOGICAL INFORMATION Not available. May be harmful to aquatic life.Ecotoxicity: Not available. May be harmful if allowed to enter drinking water intakes. Do not contaminate domestic or irrigation water supplies, lakes, streams, ponds, or rivers. Product has an unaesthetic appearance and can be a nuisance. Environmental Fate: 13. DISPOSAL CONSIDERATIONS Recover spilled material on adsorbents, such as sand or vermiculite, and place in covered containers for disposal. Deactivating Chemicals: This information applies to the material as manufactured. Reevaluation of the product may be required by the user at the time of disposal since the product uses, transformations, mixtures and processes may influence waste classification. Dispose of waste material at an approved (hazardous) waste treatment/disposal facility in accordance with applicable local, provincial and federal regulations. Do not dispose of waste with normal garbage, or to sewer systems. Waste Disposal Methods: See "Waste Disposal Methods".Safe Handling of Residues: Empty containers retain product residue and may be hazardous. Empty drums should be completely drained, properly bunged and promptly returned to a drum reconditioner. Dispose of waste material at an approved (hazardous) waste treatment/disposal facility in accordance with applicable local, provincial and federal regulations. Disposal of Packaging: 14. TRANSPORTATION INFORMATION CANADIAN TDG ACT SHIPPING DESCRIPTION: Molydag 208, Paste Brenntag Canada Inc. Date of Revision: 2007 November 30WHMIS Number : 00068497 Page 6 of 7 This product is not regulated by TDG. Label(s): Not applicable. Placard: Not applicable. ERAP Index: -----. Exemptions: None known. US DOT CLASSIFICATION (49CFR 172.101, 172.102): This product is not regulated by DOT. Label(s): Not applicable. Placard: Not applicable. CERCLA-RQ: Not available. Exemptions: None known. 15. REGULATORY INFORMATION CANADA All constituents of this product are included on the DSL.CEPA - NSNR: Not included.CEPA - NPRI: Controlled Products Regulations Classification (WHMIS): Not regulated. USA All constituents of this product are included on the TSCA inventory.Environmental Protection Act: Not regulated.OSHA HCS (29CFR 1910.1200): Text22: NFPA: Health, Fire, Reactivity (Not available.) Text22: HMIS: Health, Fire, Reactivity (Not available.) INTERNATIONAL Not available. 16. OTHER INFORMATION REFERENCES RTECS-Registry of Toxic Effects of Chemical Substances, Canadian Centre for Occupational Health and Safety RTECS database. 1. Clayton, G.D. and Clayton, F.E., Eds., Patty's Industrial Hygiene and Toxicology, 3rd ed., Vol. IIA,B,C, John Wiley and Sons, New York, 1981. 2. Supplier's Material Safety Data Sheet(s).3. CHEMINFO, through "CCINFOdisc", Canadian Centre for Occupational Health and Safety, Hamilton, Ontario, Canada.4. Guide to Occupational Exposure Values, 2005, American Conference of Governmental Industrial Hygienists, Cincinnati, 2005.5. Regulatory Affairs Group, Brenntag Canada Inc.6. The British Columbia Drug and Poison Information Centre, Poison Managements Manual, Canadian Pharmaceutical Association, Ottawa, 1981. 7. ____________________________________________________________________________________________________________ The information contained herein is offered only as a guide to the handling of this specific material and has been prepared in good faith by technically knowledgeable personnel. It is not intended to be all-inclusive and the manner and conditions of use and handling may involve other and additional considerations. No warranty of any kind is given or implied and Brenntag Canada Inc. will not be liable for any damages, losses, injuries or consequential damages which may result from the use of or reliance on any information contained herein. This Material Safety Data Sheet is valid for three years. ____________________________________________________________________________________________________________ To obtain revised copies of this or other Material Safety Data Sheets, contact your nearest Brenntag Canada Regional office. British Columbia: 20333-102B Avenue, Langley, BC, V1M 3H1 Phone: (604) 513-9009 Facsimile: (604) 513-9010 Alberta: 6628 - 45 th. Street, Leduc, AB, T9E 7C9 Phone: (780) 986-4544 Facsimile: (780) 986-1070 Manitoba: 681 Plinquet Street, Winnipeg, MB, R2J 2X2 Molydag 208, Paste Brenntag Canada Inc. Date of Revision: 2007 November 30WHMIS Number : 00068497 Page 7 of 7 Phone: (204) 233-3416 Facsimile: (204) 233-7005 Ontario: 43 Jutland Road, Toronto, ON, M8Z 2G6 Phone: (416) 259-8231 Facsimile: (416) 259-5333 Quebec: 2900 Jean Baptiste Des., Lachine, PQ, H8T 1C8 Phone: (514) 636-9230 Facsimile: (514) 636-0877 Atlantic: A-105 Akerley Boulevard, Dartmouth, NS, B3B 1R7 Phone: (902) 468-9690 Facsimile: (902) 468-3085 ____________________________________________________________________________________________________________ Prepared By: Regulatory Affairs Group, Brenntag Canada Inc., (416) 259-8231. product residue and may be hazardous. Empty drums should be completely drained, properly bunged and promptly returned to a drum reconditioner. Dispose of waste material at an approved (hazardous) waste treatment/disposal facility in accordance with applicable local, provincial and federal regulations. Disposal of Packaging: 14. TRANSPORTATION INFORMATION CANADIAN TDG ACT SHIPPING DESCRIPTION: Molydag 208, Paste Brenntag Canada Inc. Date of Revision: 2007 November 30WHMIS Number : 00068497 Page 6 of 7 This product is not regulated by TDG. Label(s): Not applicable. Placard: Not applicable. ERAP Index: -----. Exemptions: None known. US DOT CLASSIFICATION (49CFR 172.101, 172.102): This product is not regulated by DOT. Label(s): Not applicable. Placard: Not applicable. CERCLA-RQ: Not available. Exemptions: None known. 15. REGULATORY INFORMATION CANADA All constituents of this product are included on the DSL.CEPA - NSNR: Not included.CEPA - NPRI: Controlled Products Regulations Classification (WHMIS): Not regulated. USA All constituents of this product are included on the TSCA inventory.Environmental Protection Act: Not regulated.OSHA HCS (29CFR 1910.1200): Text22: NFPA: Health, Fire, Reactivity (Not available.) Text22: HMIS: Health, Fire, Reactivity (Not available